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Highly Strained, Ring-Tilted [1]Ferrocenophanes Containing Group 16 Elements in the Bridge: Synthesis, Structures, and Ring-Opening Oligomerization and Polymerization of [1]Thia- and [1]Selenaferrocenophanes

✍ Scribed by Rulkens, Ron; Gates, Derek P.; Balaishis, David; Pudelski, John K.; McIntosh, Douglas F.; Lough, Alan J.; Manners, Ian

Book ID: 121294451
Publisher: American Chemical Society
Year: 1997
Tongue: English
Weight: 318 KB
Volume: 119
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja972043u

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Transition Metal-Catalyzed Ring-Opening

Transition Metal-Catalyzed Ring-Opening Polymerization of Silicon-Bridged [1]Ferrocenophanes in the Presence of Functional Silanes: Molecular Weight Control and Synthesis of Telechelic Poly(ferrocenylsilanes)

✍ Alexandra Bartole-Scott; Rui Resendes; Ian Manners 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 162 KB

## Abstract The transition metal‐catalyzed ring‐opening polymerization of dimethyl[1]silaferrocenophane (fcSiMe~2~) (1), fc = Fe(__η__‐C~5~H~4~)~2~), in the presence of MePhSiH~2~, or the chlorosilanes ClMe~2~SiH, ClMePhSiH, or ClPh~2~SiH has been shown to allow access to poly(ferrocenylsilane)s R^