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Highly strained hydrocarbons. The photolysis of Δ2-cyclopentenyldiazomethane

✍ Scribed by D.M. Lemal; K.S. Shim


Publisher
Elsevier Science
Year
1965
Tongue
French
Weight
27 KB
Volume
6
Category
Article
ISSN
0040-4039

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✦ Synopsis


Tetrahedron Letters No.44, 323J-5236 (1964) p.W57, the aooigments of the two n,m.r eignale attributable to the methinc protons oiLwere inadvertently switched with rerpect to the model coltpounds (footnote 6) on which they were based. p.5235, the double bond in miming in the form18 for A2-cyclopentenyldiaeomethane. A.CBATTlSlJKE, B.DAS, C.P.DDTTA and K.S.II[IKBIpBJEE: Steroid alkaloids of Saracococa prmiforais Lindl.


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Highly Strained 2,3-Bridged 2H-Azirines
✍ Prof. Klaus Banert; Dr. Barbara Meier; Dr. Enrico Penk; Dr. Biswajit Saha; Prof. 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 287 KB

## Abstract Substituted 1‐azidocyclopentenes and 1‐azidocyclohexenes were photolyzed to generate 2,3‐bridged 2__H__‐azirines. In the case of bridgehead azirines with a six‐membered carbocycle, detection by NMR spectroscopic analysis was possible, whereas even kinetically stabilized bridgehead aziri