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Highly Strained Bicyclic Systems. VI. 1Reactions of 1,5,5-Trimethylbicyclo[2.1.1]-hexane-6-carboxylic Acid and the Synthesis of Bicyclo[2.1.1]hexyl Analogs of Borneol and Isoborneol 2

✍ Scribed by Meinwald, Jerrold.; Lewis, Arthur.; Gassman, Paul G.

Book ID: 126808647
Publisher: American Chemical Society
Year: 1962
Tongue: English
Weight: 920 KB
Volume: 84
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja00865a020

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Previously (2) we described that diphenyltricyclo-[1.1.1.04'5 lpentanone underwent facile carbon-carbon bond cleavage reactions even under mild conditions. Its homolog, 8,6-diphenyltricyclo[2.1.1.05q6]hexan-2-one, however, has been found to be relatively stable and to react with carbonyl reagents to

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