Highly stereoselective total synthesis of .beta.-ribofuranosylmalonate
β Scribed by Katagiri, Nobuya; Akatsuka, Hidenori; Haneda, Toru; Kaneko, Chikara; Sera, Akira
- Book ID
- 120816302
- Publisher
- American Chemical Society
- Year
- 1988
- Tongue
- English
- Weight
- 925 KB
- Volume
- 53
- Category
- Article
- ISSN
- 0022-3263
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carried out by treating 5 with 1.4-dibromobutane in dimethylformamide (DHF) in the presence of potassium tert-butoxide to afford 6 in 39% yield. Then focus was turned to the synthesis of deoxysesbanine (12). On the contrary to the easy alkoxycarbonylation of 4, treatment of 7 under the same reaction