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Highly stereoselective synthesis of ??-unsaturated ketones by CeCl3 mediated addition of grignard reagents to ?-enamino ketones

✍ Scribed by Bartoli, Giuseppe; Cimarelli, Cristina; Marcantoni, Enrico; Palmieri, Gianni; Petrini, Marino


Book ID
115497658
Publisher
The Royal Society of Chemistry
Year
1994
Tongue
English
Weight
233 KB
Volume
6
Category
Article
ISSN
0022-4936

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A Stereoselective Synthesis of (E)-Ξ±, Ξ²-
✍ Prof. Dr. Giuseppe Bartoli; Dr. Enrico Marcantoni; Prof. Dr. Marino Petrini; Dr. πŸ“‚ Article πŸ“… 1996 πŸ› John Wiley and Sons 🌐 English βš– 735 KB

## Abstract Stereoselective construction of trisubstituted alkenes has wide applicability to the synthesis of many natural products Specifically, β‐disubstituted enones are important functionalized trisubstituted alkene targets. The reaction of organocerium reagents with secondary β‐enamino ketones