Highly stereoselective synthesis of cyclopentanes bearing four stereocentres by a rhodium carbene-initiated domino sequence

ChemInform Abstract: Asymmetric Synthesi

ChemInform Abstract: Asymmetric Synthesis of Highly Functionalized Cyclopentanes by a Rhodium- and Scandium-Catalyzed Five-Step Domino Sequence.

✍ Brendan T. Parr; Zhanjie Li; Huw M. L. Davies 📂 Article 📅 2012 🏛 John Wiley and Sons ⚖ 83 KB 👁 1 views

Asymmetric Synthesis of Highly Functionalized Cyclopentanes by a Rhodiumand Scandium-Catalyzed Five-Step Domino Sequence. -Highly functionalized cyclopentanes with four new stereogenic centers are synthesized and obtained as single diastereomers by the present new method involving five distinct step