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Highly Stereoselective Synthesis of Conjugated Polyenes via a Homocoupling Reaction of Unsaturated Silanes

✍ Scribed by Babudri, Francesco; Cicciomessere, Angela R.; Farinola, Gianluca M.; Fiandanese, Vito; Marchese, Giuseppe; Musio, Roberta; Naso, Francesco; Sciacovelli, Oronzo

Book ID
126904688
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
304 KB
Volume
62
Category
Article
ISSN
0022-3263

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Lithiated 2,4,4-trimethyl-2-oxazoline 2a and 2-chloromethyl-4,4-dimethyl-2-oxazoline 2b react smoothly with a number of nitrones 3 to produce a,b-unsaturated oxazolines 6 and 7 highly stereoselectively.