The reaction of a-methylthio aldehydes 4(R=1°, 2') with allyltriphenylstannane 5 in the presence of SnC14 gave anti-8-methylthio alcohols 6 in excellent selectivity. In connection with the recent findings that conversion of B-alkylthio alcohols 2 and 3 into olefins' or epoxides 2 proceeds with comp
✦ LIBER ✦
Highly stereoselective reduction of α-methylthio and α-phenylthio ketones synthesis of syn- and anti-β-methylthio- and β-phenylthioalcohols
✍ Scribed by Masayuki Shimagaki; Tadashi Maeda; Yuji Matsuzaki; Isaburo Hori; Tadashi Nakata; Takeshi Oishi
- Publisher
- Elsevier Science
- Year
- 1984
- Tongue
- French
- Weight
- 262 KB
- Volume
- 25
- Category
- Article
- ISSN
- 0040-4039
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