Highly stereoselective intramolecular epoxidation in unsaturated oxaziridines

✍ Scribed by Alan Armstrong; Alistair G. Draffan

• Book ID: 104261554
• Publisher: Elsevier Science
• Year: 1999
• Tongue: French
• Weight: 262 KB
• Volume: 40
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/s0040-4039(99)00771-6

✦ Synopsis

Highly stereoselective intramolecular epoxidation is observed in unsaturated oxaziridines v/a oxaziridinium salts. The observed selectivities are consistent with a spiro transition state for the intramolecular epoxidation.