✦ LIBER ✦
Highly stereoselective approach to chiral building block possessing three contiguous asymmetric centers. Preparation of four possible diastereomers of β,β′-dimethyl-bis-homoallylic alcohol derivative
✍ Scribed by Keisuke Suzuki; Eiji Katayama; Katsuhiko Tomooka; Takashi Matsumoto; Gen-ichi Tsuchihashi
- Publisher
- Elsevier Science
- Year
- 1985
- Tongue
- French
- Weight
- 247 KB
- Volume
- 26
- Category
- Article
- ISSN
- 0040-4039
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✦ Synopsis
AZZ four diastereomers of chiral alcohol 2 with three contiguous chiral centers were stereoselectiveZy prepared via diastere~selective addition of nucleophiles (crotyl metal or H-J to n-methyZ-B,y-unsaturated carbonyl compounds 1.