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Highly Stereoselective Aldol Condensation Using an Enantioselective Chiral Enolate

โœ Scribed by Prof. Dr. Satoru Masamune; Dr. Sk. Asrof Ali; Dr. David L. Snitman; David S. Garvey


Publisher
John Wiley and Sons
Year
1980
Tongue
English
Weight
233 KB
Volume
19
Category
Article
ISSN
0044-8249

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๐Ÿ“œ SIMILAR VOLUMES


Enantioselective aldol condensations: Th
โœ Ian Paterson; M.Anne Lister; Cynthia K McClure ๐Ÿ“‚ Article ๐Ÿ“… 1986 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 309 KB

Aldol condensation between diethylketone and simple aldehydes using (lpc)2BOTfliPr2NEt in CH,CI, gives syn-adducts in good ee (66-90%) and with high diastereoselectivity (290%). Other chiral dialkylboron triflate reagents examined give lower ees. The aldol condensation reaction of boron enolates, l