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Highly stereo- and regioselective palladium-catalyzed syntheses of (3E,Z)-,(3E,5E)-, and (3Z,5E)-1,3,5-undecatriene

✍ Scribed by Bianca Patrizia Andreini; Massimiliano Benetti; Adriano Carpita; Renzo Rossi


Publisher
Elsevier Science
Year
1987
Tongue
French
Weight
753 KB
Volume
43
Category
Article
ISSN
0040-4020

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A simple stereoselective synthesis of β€œG
✍ Christian Chapuis πŸ“‚ Article πŸ“… 1992 πŸ› Elsevier Science 🌐 French βš– 243 KB

A new synthesis of (3E, 5Z)-1.3,5-undecaniene (2) is presented. based on a Munnich addition to 1.4 decadiyne, followed by L&&r hydtogenation and H&aan elimbtadon. 'PItis "one pot" coupling of C7+C3+Cl syntbons affords 2 stereochemically pure. Following thek discovery in the essential oil of galbanum