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Highly stereo- and regioselective alkylation of alkylidenemalonates. Application to the synthesis of (.+-.)-canadensolide

✍ Scribed by Tsuboi, Sadao; Muranaka, Koichi; Sakai, Takashi; Takeda, Akira


Book ID
121418030
Publisher
American Chemical Society
Year
1986
Tongue
English
Weight
410 KB
Volume
51
Category
Article
ISSN
0022-3263

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Highly stereo- and regioselective synthe
✍ Mariusz Majchrzak; Yujiro Itami; Bogdan Marciniec; Piotr Pawluc πŸ“‚ Article πŸ“… 2000 πŸ› Elsevier Science 🌐 French βš– 78 KB

RuCl 2 (CO) 3 ] 2 catalyzed cross-coupling polycondensation of 1,4-bis(vinyldimethylsilyl)benzen appears to be a new, very efficient, method for highly stereo-and regioselective synthesis of phen silylene-vinylene polymers (B).