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Highly stabilized radicals: benzylic radicals in polycyclic aromatic systems

โœ Scribed by McMillen, Donald F.; Trevor, Paula L.; Golden, David M.

Book ID
127284722
Publisher
American Chemical Society
Year
1980
Tongue
English
Weight
325 KB
Volume
102
Category
Article
ISSN
0002-7863

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The rates of free radical reduction of a series of anthracene derivatives and 1-phenyl-4-bromodecane with tributyltin hydride are mediated by the remote aromatic substituent in an apparent through-space interaction. Density functional calculations suggest that this enhancement is not due to direct s