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Highly Selective Oxidation of Organosilanes to Silanols with Hydrogen Peroxide Catalyzed by a Lacunary Polyoxotungstate

✍ Scribed by Ryo Ishimoto; Keigo Kamata ; Noritaka Mizuno

Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
359 KB
Volume
121
Category
Article
ISSN
0044-8249

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📜 SIMILAR VOLUMES

Highly Selective Oxidation of Organosila
Highly Selective Oxidation of Organosilanes to Silanols with Hydrogen Peroxide Catalyzed by a Lacunary Polyoxotungstate
✍ Ryo Ishimoto; Keigo Kamata ; Noritaka Mizuno 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 359 KB 👁 1 views

Organosilicon compounds have attracted much attention, and silanols are widely utilized as building blocks for the production of silicon-based polymer materials and organic donors in metal-catalyzed cross-coupling reactions. [1, 2] Silanols are conventionally synthesized by hydrolysis of chlorosilan

Oxidation of Benzene to Phenol with Hydr
Oxidation of Benzene to Phenol with Hydrogen Peroxide Catalyzed by a Modified Titanium Silicalite (TS-1B)
✍ Daniele Bianchi; Luigi Balducci; Rossella Bortolo; Rino D'Aloisio; Marco Ricci; 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 170 KB 👁 2 views

## Abstract The hydroxylation of benzene to phenol with hydrogen peroxide was investigated using different solvents and a series of catalysts, obtained by modification of titanium silicalite (TS‐1). The best results were obtained after post‐synthesis treatment of TS‐1 with NH~4~HF~2~ and H~2~O~2~.