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Highly selective generation of urethanes from amines, carbon dioxide and alkyl chlorides

โœ Scribed by McGhee, William D.; Pan, Yi; Riley, Dennis P.


Book ID
121299418
Publisher
The Royal Society of Chemistry
Year
1994
Tongue
English
Weight
257 KB
Volume
6
Category
Article
ISSN
0022-4936

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The synthesis of alkyl carbamates from p
โœ Maurizio Selva; Pietro Tundo; Alvise Perosa ๐Ÿ“‚ Article ๐Ÿ“… 2002 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 60 KB

At 130ยฐC and in the presence of compressed CO 2 , primary aliphatic amines [RNH 2 , R=C 10 H 21 , C 8 H 17 , cHex, 1-(C 10 H 7 )CH 2 ] react with organic carbonates (R%OCO 2 R%; R%=Me, Et) to give alkyl carbamates (RNHCO 2 R%, 1). Although CO 2 promotes the reaction also at a low pressure, good yiel