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Highly selective aerobic oxidation of primary amines to nitriles by ruthenium hydroxide

✍ Scribed by Yuan Zhang; Kunling Xu; Xiaorong Chen; Tongjie Hu; Yanpeng Yu; Junli Zhang; Jun Huang


Book ID
116343501
Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
203 KB
Volume
11
Category
Article
ISSN
1566-7367

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Aerobic Oxidative Transformation of Prim
✍ He, Jinling; Yamaguchi, Kazuya; Mizuno, Noritaka πŸ“‚ Article πŸ“… 2011 πŸ› American Chemical Society 🌐 English βš– 866 KB

In the presence of an easily prepared supported ruthenium hydroxide catalyst, Ru(OH)(x)/Al(2)O(3), various kinds of structurally diverse primary azides including benzylic, allylic, and aliphatic ones could be converted into the corresponding nitriles in moderate to high yields (13 examples, 65-94% y