Highly Selective 1,6-Addition of Aryl Boronic Acids to α,β,γ,δ-Unsaturated Carbonyl Compounds Catalyzed by an Iridium Complex

✍ Scribed by Takahiro Nishimura; Yuichi Yasuhara; Tamio Hayashi

• Publisher: John Wiley and Sons
• Year: 2006
• Tongue: English
• Weight: 110 KB
• Volume: 45
• Category: Article
• ISSN: 0044-8249
• DOI: 10.1002/anie.200601719

✦ Synopsis

under H 2 (1 atm) in EtOAc (2.0 mL) at room temperature for 3 h to give 6-phenyl-2-heptanone (83.0 mg, 86 %).