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Highly Regioselective Ring Opening of Epoxides with Polymer Supported Phenoxide and Naphthoxide Anions

โœ Scribed by Tamami, B.; Iranpoor, N.; Rezaei, R.

Book ID
121284280
Publisher
Taylor and Francis Group
Year
2004
Tongue
English
Weight
125 KB
Volume
34
Category
Article
ISSN
0039-7911

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Highly regioselective ring opening of ep
Highly regioselective ring opening of epoxides and aziridines using cerium(III) chloride
โœ Gowravaram Sabitha; R Satheesh Babu; M Rajkumar; Ch.Srinivas Reddy; J.S Yadav ๐Ÿ“‚ Article ๐Ÿ“… 2001 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 104 KB

A wide variety of epoxides and aziridines were converted to the corresponding b-halohydrins and b-haloamines using cerium(III) chloride and the cerium(III) chloride/NaI system in acetonitrile. The reactions were highly regioselective and efficient with excellent yields under mild and neutral reactio