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Highly Regioselective Oxidative Polymerization of 4-Phenoxyphenol to Poly(1,4-phenylene oxide) Catalyzed by Tyrosinase Model Complexes

✍ Scribed by Higashimura, Hideyuki; Fujisawa, Kiyoshi; Moro-oka, Yoshihiko; Kubota, Masaaki; Shiga, Akinobu; Terahara, Atsushi; Uyama, Hiroshi; Kobayashi, Shiro


Book ID
111647151
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
63 KB
Volume
120
Category
Article
ISSN
0002-7863

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Poly(4,6-di-n-butoxy-1,3-phenylene) ( 6) was prepared by oxidative coupling polymerization of 1,3-di-n-butoxybenzene ( 1) or 2,2,4,4-tetra-n-butoxy biphenyl (3). Polymerizations were conducted in nitrobenzene in the presence of FeCl 3 at room temperature and produced polymers with number-average mol