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Highly regioselective iodoperfluoroalkylation of allenes with perfluoroalkyl iodides upon irradiation with near-UV light

✍ Scribed by Akiya Ogawa; Motohiro Imura; Nagisa Kamada; Toshikazu Hirao

Book ID
104230281
Publisher
Elsevier Science
Year
2001
Tongue
French
Weight
73 KB
Volume
42
Category
Article
ISSN
0040-4039

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✦ Synopsis

Upon irradiation through Pyrex with a xenon lamp (hw>300 nm), perfluoroalkyl iodides add to terminal allenes regioselectively to afford the corresponding iodoperfluoroalkylated products, where perfluoroalkyl and iodo groups are selectively introduced into the terminal and central carbons of allenes, respectively.

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