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Highly regioselective diels-alder reactions of 2-trimethylsilylmethyl- and 2-trimethylstannylmethyl-1,3-butadiene

✍ Scribed by Akira Hosomi; Masaki Saito; Hideki Sakurai


Book ID
108384588
Publisher
Elsevier Science
Year
1980
Tongue
French
Weight
205 KB
Volume
21
Category
Article
ISSN
0040-4039

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2-Trimethylsilylmethyl-1,3\_butadiene undergoes highly regioselective Diels-Alder reactions with dienophiles such as acrolein and methyl vinyl ketone catalyzed by aluminum chloride in which the "para" isomers are obtained almost exclusively. The adducts are converted readily to a variety of naturall

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