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Highly Regioselective C(3) Opening of an Aromatic 2,3-Epoxy Alcohol with Sodium Phenoxides or Thiophenoxides (= Benzenethiolates) Supported by β-Cyclodextrin in Water.

✍ Scribed by Mendu Narender; Majjigapu Somi Reddy; Yadavalli Venkata Durga Nageswar; Kakulapati Rama Rao


Publisher
John Wiley and Sons
Year
2007
Weight
20 KB
Volume
38
Category
Article
ISSN
0931-7597

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Highly Regioselective C(3) Opening of an
✍ Mendu Narender; Majjigapu Somi Reddy; Yadavalli Venkata Durga Nageswar; Kakulapa 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 German ⚖ 63 KB

## Abstract A simple and mild procedure was developed for the first time for the C(3)‐selective ring opening of an aromatic 2,3‐epoxy alcohol, __i.e.__, of __trans__‐3‐phenyloxirane‐2‐methanol (**1**), with sodium phenoxides or thiophenoxides (=benzenethiolates) **2** supported by __β__‐cyclodextri