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Highly Regio- and Stereoselective Synthesis of Tetrasubstituted Olefins by the Three-Component Tandem Reaction of Allylzinc Bromide, Acetylenic Sulfone, and Halohydrocarbon.

✍ Scribed by Meihua Xie; Jialiang Wang; Xiaoxia Gu; Ying Sun; Shaowu Wang


Publisher
John Wiley and Sons
Year
2006
Weight
31 KB
Volume
37
Category
Article
ISSN
0931-7597

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✍ E. J. COREY; J. LEE; B. E. ROBERTS πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 38 KB πŸ‘ 2 views

The Application of the Shapiro Reaction to the Stereoselective Synthesis of E-Trisubstituted Olefins for Cation-Olefin Cyclization by Three Component Coupling. -Various trisubstituted olefins are synthesized by copper-mediated coupling of acetone trisylhydrazones (II) and (X) with alkyl or aryl hal