Highly Reactive Porphyrin−Iron−Oxo Derivatives Produced by Photolyses of Metastable Porphyrin−Iron(IV) Diperchlorates

Enhanced Reactivities of Iron(IV)-Oxo Po

Enhanced Reactivities of Iron(IV)-Oxo Porphyrin π-Cation Radicals in Oxygenation Reactions by Electron-Donating Axial Ligands

✍ Yaeun Kang; Hui Chen; Yu Jin Jeong; Wenzhen Lai; Eun Hae Bae; Sason Shaik; Wonwo 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 583 KB

## Abstract The proximal axial ligand in heme iron enzymes plays an important role in tuning the reactivities of iron(IV)‐oxo porphyrin π‐cation radicals in oxidation reactions. The present study reports the effects of axial ligands in olefin epoxidation, aromatic hydroxylation, alcohol oxidation,