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Highly general stereo-, regio-, and chemo-selective synthesis of terminal and internal conjugated enynes by the Pd-catalysed reaction of alkynylzinc reagents with alkenyl halides

โœ Scribed by King, Anthony O.; Okukado, Nobuhisa; Negishi, Ei-ichi


Book ID
111980260
Publisher
The Royal Society of Chemistry
Year
1977
Tongue
English
Weight
193 KB
Volume
19
Category
Article
ISSN
0022-4936

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A highly stereo- , regio- , and chemosel
โœ Nobuhisa Okukado; David E. Van Horn; William L. Klima; Ei-ichi Negishi ๐Ÿ“‚ Article ๐Ÿ“… 1978 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 211 KB

We have recently reported a highly stereoand regioselective procedure for the synthesis of conjugated dienes by a Pd-catalyzed reaction of alkenylalanes with alkenyl halides2 (eq 1: MLn = AL(Bu-~)~).