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Highly Functionalized Cyclobutanols by Samarium(II) Iodide Induced Radical Cyclizations of Carbohydrate-Derived Unsaturated Ketones.

✍ Scribed by D. Bradley G. Williams; Kevin Blann


Publisher
John Wiley and Sons
Year
2004
Weight
20 KB
Volume
35
Category
Article
ISSN
0931-7597

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Highly Functionalised Cyclobutanols by S
✍ D. Bradley G. Williams; Kevin Blann 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 127 KB

## Abstract Certain carbohydrates have been found to be excellent precursors for the samarium diiodide‐mediated 4‐__exo__‐__trig__ cyclisation reaction of their keto‐olefin derivatives, which were readily prepared in a few easy steps. The cyclisation was found to be stereoselective, affording __cis