Crosslinkable fluorinated poly(arylene ethers) (FPAE-Fn-PEP) with high transparency and high thermal stability have been investigated for low-loss optical waveguide materials. FPAE-Fn-PEP bearing phenyl ethynyl moiety at the polymer chain end were synthesized by the reaction of 4,4Ј-(hexafluoro-isop
Highly Fluorinated and Crosslinkable Dendritic Polymer for Photonic Applications
✍ Scribed by Hong Ma; Jingdong Luo; Seok Ho Kang; Sharon Wong; Jae Wook Kang; Alex K.-Y. Jen; Rick Barto; Curtis W. Frank
- Publisher
- John Wiley and Sons
- Year
- 2004
- Tongue
- English
- Weight
- 173 KB
- Volume
- 25
- Category
- Article
- ISSN
- 1022-1336
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✦ Synopsis
Abstract
Summary: A novel crosslinkable dendritic polymer has been synthesized by the thermal polymerization of peripheral aryl trifluorovinyl ether moieties of a highly fluorinated dendrimer. The resulting perfluorocyclobutane(PFCB)‐containing dendritic polymer exhibited excellent processability, low optical loss (0.36 dB · cm^−1^ at 1 310 nm with 1% dye doping), high thermal stability, and good solvent resistance for waveguide‐based photonic applications.
Structure of the crosslinkable fluorinated dendrimer synthesized.
imageStructure of the crosslinkable fluorinated dendrimer synthesized.
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