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Highly enhanced superconducting properties of Bi-2212 by Y and Pb co-doping

✍ Scribed by P.M. Sarun; R. Shabna; S. Vinu; A. Biju; U. Syamaprasad


Publisher
Elsevier Science
Year
2009
Tongue
English
Weight
752 KB
Volume
404
Category
Article
ISSN
0921-4526

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✦ Synopsis


The effects of Y and Pb co-doping on phase evolution, microstructure, electrical and superconducting properties of Bi-2212 have been studied. The results show that Y 3+ ions enter into the crystal structure by replacing Ca 2+ and/or Sr 2+ ions, and hence reduce hole concentration in the electronic structure of the system. Y and Pb co-doping result in the reduction of c-axis resistivity due to strong Josephson coupling between the Cu-O 2 layers at lower Y contents. The T C and J C are significantly enhanced for optimum Y concentration in Pb doped Bi-2212. The variations in the electrical and superconducting properties are due to the structural as well as electronic inhomogeneities and changes in charge carrier concentration due to Pb and Y co-doping.


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Superconducting and crystallographic pro
✍ A. Jeremie; J.-C. Grivel; R. FlΓΌkiger πŸ“‚ Article πŸ“… 1994 πŸ› Elsevier Science 🌐 English βš– 329 KB

Superconducting Bi2.xPbxSr2CaCu20 x (noted Bi,F~2212)) has been processed in air at 860Β°C with a nominal composition of Bi 1.72pbo.34srl.83Cao.97Cl12.13Ox in contrast to the literature where this phase was produced in argon around 740Β°C. With the aim of transforming this phase into Bi,F~b(2223) (ano