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Highly enantioselective oxidation of cyclic dithioacetals by using a Ti(salen) and urea·hydrogen peroxide system

✍ Scribed by Tomoaki Tanaka; Bunnai Saito; Tsutomu Katsuki

Book ID
104250954
Publisher
Elsevier Science
Year
2002
Tongue
French
Weight
62 KB
Volume
43
Category
Article
ISSN
0040-4039

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✦ Synopsis

Asymmetric oxidation of 2-substituted 1,3-dithianes using a Ti(salen) and urea•hydrogen peroxide system in methanol was found to proceed with high enantioselectivity to give the corresponding mono-sulfoxides.

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