Highly Enantioselective Intramolecular Cyclopropanation Reactions of N -Allylic- N -methyldiazoacetamides Catalyzed by Chiral Dirhodium(II) Carboxamidates
β Scribed by Doyle, Michael P.; Kalinin, Alexey V.
- Book ID
- 120422783
- Publisher
- American Chemical Society
- Year
- 1996
- Tongue
- English
- Weight
- 248 KB
- Volume
- 61
- Category
- Article
- ISSN
- 0022-3263
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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v
A series of racemic dirhodium(II) compounds with two ortho-metalated aryl phosphine ligands in a head-to-tail arrangement Rh 2 (O 2 CR) 2 (pc) 2 (pc=ortho-metalated aryl phosphine) (1a-k) were tested in the regio-and stereoselective cyclopropanation of racemic 1-diazo-6-methyl-3-(2-propenyl)-5-hepte