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Highly Enantioselective Cyanoformylation of Aldehydes Catalyzed by a Mononuclear Salen-Ti(OiPr)4 Complex Produced In Situ

✍ Scribed by Shi-Kui Chen; Dan Peng; Hui Zhou; Li-Wei Wang; Fu-Xue Chen; Xiao-Ming Feng


Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
144 KB
Volume
2007
Category
Article
ISSN
1434-193X

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Highly enantioselective addition of term
✍ Li Qiu; Quan Wang; Li Lin; Xiaodong Liu; Xianxing Jiang; Qingyang Zhao; Guowen H πŸ“‚ Article πŸ“… 2009 πŸ› John Wiley and Sons 🌐 English βš– 124 KB

## Abstract A new catalytic system, generated from the readily available and inexpensive β‐sulfonamide alcohol L\*, Ti(O^i^Pr)~4~, Et~2~Zn, and tertiary amine base (R~3~N), effectively catalyzes the enantioselective addition of various terminal alkynes including some quite challenging alkynes to al