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Highly Enantioselective Claisen Rearrangement of Imidates Derived from Primary Allyl Alcohols †

✍ Scribed by Metz, Peter; Hungerhoff, Benno

Book ID
126161764
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
217 KB
Volume
62
Category
Article
ISSN
0022-3263

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A new cobaltocenyl oxazoline palladacycle compound was prepared for the enantioselective aza-Claisen rearrangement of allylic imidates. Studies on the effect of face-blocking and the mechanism of the reaction were carried out.