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Highly Enantioselective Carbonyl-ene Reactions Catalyzed by In(III)−PyBox Complex

✍ Scribed by Zhao, Jun-Feng; Tsui, Hoi-Yan; Wu, Pei-Jia; Lu, Jun; Loh, Teck-Peng

Book ID
120535225
Publisher
American Chemical Society
Year
2008
Tongue
English
Weight
104 KB
Volume
130
Category
Article
ISSN
0002-7863

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Significant counterion effect of the In(III)–pybox complex in highly enantioselective carbonyl-ene reactions of ethyl glyoxylate
✍ Jun-Feng Zhao; Teguh-Budiono W. Tjan; Teck-Peng Loh 📂 Article 📅 2010 🏛 Elsevier Science 🌐 French ⚖ 973 KB

A highly efficient enantioselective carbonyl-ene reaction of ethyl glyoxylate catalyzed by an In(III)-pybox complex, which is designed based on the counterion effect, is reported. Reactions of both aliphatic and aromatic 1,1-disubstituted olefins proceed smoothly to give enantioenriched homoallylic