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Highly Enantioselective Addition of Phenylacetylene to Aldehydes Catalyzed by a Camphorsulfonamide Ligand

✍ Scribed by Xu, Zhaoqing; Chen, Chao; Xu, Jiangke; Miao, Mingbo; Yan, Wenjin; Wang, Rui

Book ID: 127330220
Publisher: American Chemical Society
Year: 2004
Tongue: English
Weight: 38 KB
Volume: 6
Category: Article
ISSN: 1523-7060
DOI: 10.1021/ol036418u

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The enantioselective formation of C À C bonds is an area of intense research. [1,2] The asymmetric addition of alkynyl reagents to aldehydes is very useful for the synthesis of chiral secondary propargyl alcohols, which are important building blocks for many chiral organic compounds. [3] Several stu