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Highly Efficient Syntheses of the Phytoalexin-Elicitor Active β-(1→3)-Branched β-(1→6)-Linked Heptaglucose and Its Dodecyl Glycoside.

✍ Scribed by Yuetao Yi; Zhongxuan Zhou; Jun Ning; Fanzuo Kong; Jianqiang Li


Publisher
John Wiley and Sons
Year
2003
Weight
59 KB
Volume
34
Category
Article
ISSN
0931-7597

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Stereocontrolled synthesis of sulfur-lin
✍ Marie-Odile Contour-Galcera; Yili Ding; Carmen Ortiz-Mellet; Jacques Defaye 📂 Article 📅 1996 🏛 Elsevier Science 🌐 English ⚖ 497 KB

The branched, sulfur-linked tetrasaccharide S-(beta-D-glucopyranosyl)-(1-->3)-S-[(6-S-beta-D-glucopyranosyl)-3,6-dit hio- beta-D-glucopyranosyl]-(1-->3)-S-3-thio-D-glucopyranose (9) has been conveniently prepared by SN2 displacement of the triflate group in 1,2:5,6-di-O-isopropylidene-3-O-trifluorom