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Highly Efficient Phosphapalladacyclic Catalysts for the Hydroarylation of Norbornene

✍ Scribed by Jean Michel Brunel; Andreas Heumann; Gérard Buono


Publisher
John Wiley and Sons
Year
2000
Tongue
English
Weight
112 KB
Volume
39
Category
Article
ISSN
0044-8249

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## Abstract Ring‐opening metathesis polymerization (ROMP) of norbornene catalyzed by niobium(V) __N__,__N__‐dialkylcarbamates Nb(O~2~CNR~2~)~5~, __R__ = Et (**1**), Me (**2**) was studied in the presence of methylaluminoxane (MAO) as a cocatalyst. These novel catalytic systems resulted very active