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Highly efficient oxidation of benzyl alcohols using the catalytic system sulfoxide/oxo-complexes

โœ Scribed by Sousa, Sara C.A.; Bernardo, Joana R.; Fernandes, Ana C.

Book ID
120423365
Publisher
Elsevier Science
Year
2012
Tongue
French
Weight
295 KB
Volume
53
Category
Article
ISSN
0040-4039

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Highly efficient and chemoselective redu
Highly efficient and chemoselective reduction of sulfoxides using the system silane/oxo-rhenium complexes
โœ Sara C.A. Sousa; Ana C. Fernandes ๐Ÿ“‚ Article ๐Ÿ“… 2009 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 281 KB

This work reports a novel method for the reduction of sulfoxides with silanes catalyzed by high valent oxo-rhenium(V) and (VII) complexes. The catalytic system PhSiH 3 /ReIO 2 (PPh 3 ) 2 (1 mol %) proved to be highly efficient for the reduction of a wide range of sulfoxides in excellent yields under