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Highly Efficient CH Hydroxylation of Carbonyl Compounds with Oxygen under Mild Conditions

✍ Scribed by Liang, Yu-Feng; Jiao, Ning

Book ID
125817269
Publisher
John Wiley and Sons
Year
2013
Tongue
English
Weight
413 KB
Volume
126
Category
Article
ISSN
0044-8249

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Highly Efficient Hydroxylation of Carbon
Highly Efficient Hydroxylation of Carbonyl Compounds with Dimethyldioxirane
✍ Adam, Waldemar ;Prechtl, Frank 📂 Article 📅 1991 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 485 KB

The enolates and/or enols of ketones, esters, P-diketones, P-0x0 esters, and p-0x0 lactones were transformed by dimethyldioxirane (isolated in acetone solution or generated in situ) into their a-hydroxy compounds in good to excellent yields. The direct hydroxylation of the enols was significantly en