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Highly Efficient B(C 6 F 5 ) 3 -Catalyzed Hydrosilylation of Olefins †

✍ Scribed by Rubin, Michael; Schwier, Todd; Gevorgyan, Vladimir


Book ID
126607668
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
73 KB
Volume
67
Category
Article
ISSN
0022-3263

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Highly efficient cleavage of epoxides ca
✍ S. Chandrasekhar; Ch. Raji Reddy; B. Nagendra Babu; G. Chandrashekar 📂 Article 📅 2002 🏛 Elsevier Science 🌐 French ⚖ 211 KB

A highly effective protocol for ring opening of epoxides with allyl and propargyl alcohols, aniline and thiophenol in the presence of catalytic amounts of B(C 6 F 5 ) 3 has been developed. Benzyl, tetrahydropyranyl, tert-butyldimethyl silyl protecting groups were stable under the reaction conditions