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Highly Efficient Antibody-Catalyzed Deuteration of Carbonyl Compounds

โœ Scribed by Avidor Shulman; Danielle Sitry; Hagit Shulman; Ehud Keinan


Publisher
John Wiley and Sons
Year
2002
Tongue
English
Weight
558 KB
Volume
8
Category
Article
ISSN
0947-6539

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Highly Efficient Hydroxylation of Carbon
โœ Adam, Waldemar ;Prechtl, Frank ๐Ÿ“‚ Article ๐Ÿ“… 1991 ๐Ÿ› Wiley (John Wiley & Sons) ๐ŸŒ English โš– 485 KB

The enolates and/or enols of ketones, esters, P-diketones, P-0x0 esters, and p-0x0 lactones were transformed by dimethyldioxirane (isolated in acetone solution or generated in situ) into their a-hydroxy compounds in good to excellent yields. The direct hydroxylation of the enols was significantly en