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Highly Efficient and Versatile Pd-Catalyzed Direct Alkynylation of Both Azoles and Azolines

✍ Scribed by Kim, Seok Hwan; Chang, Sukbok

Book ID
120274372
Publisher
American Chemical Society
Year
2010
Tongue
English
Weight
261 KB
Volume
12
Category
Article
ISSN
1523-7060

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✍ Bartolo Gabriele; Lucia Veltri; Vito Maltese; Rosella Spina; Raffaella Mancuso; 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 245 KB 👁 1 views

## Abstract Isoquinoline‐4‐carboxylic esters **3** and isochromene‐4‐carboxylic esters **4** have been conveniently prepared by direct PdI~2~‐catalyzed oxidative heterocyclization/alkoxycarbonylation of readily available (2‐alkynylbenzylidene)amine derivatives. In particular, (2‐alkynylbenzylidene)