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Highly efficient and convenient asymmetric hydrosilylation of ketones catalyzed with zinc Schiff base complexes

✍ Scribed by Shuai Liu; Jiajian Peng; Hu Yang; Ying Bai; Jiayun Li; Guoqiao Lai

Book ID
113929221
Publisher
Elsevier Science
Year
2012
Tongue
French
Weight
932 KB
Volume
68
Category
Article
ISSN
0040-4020

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## Abstract magnified image Chiral macrocyclic tetra‐ and hexamine macrocycles derived from __trans__‐1,2‐diaminocyclohexane (DACH) in complexes with diethylzinc efficiently catalyze the asymmetric hydrosilylation of aryl alkyl ketones with enantiomeric excess of the product up to 89%. The cyclic