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Highly Diastereoselective Total Syntheses of (+)-7-Epigoniodiol, (−)-8-Epigoniodiol, and (+)-9-Deoxygoniopypyrone

✍ Scribed by Kumaraswamy, Gullapalli; Satish Kumar, Rangaraju


Book ID
120535579
Publisher
John Wiley and Sons
Year
2013
Tongue
German
Weight
240 KB
Volume
96
Category
Article
ISSN
0018-019X

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Total Syntheses of Angular [7]-, [8]-, a
✍ Sangdon Han; D. Ryan Anderson; Andrew D. Bond; Hiufung V. Chu; Raymond L. Disch; 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 129 KB

We have reported on the total syntheses of the first helical phenylenes (heliphenes), angular [6]-(1) and [7]phenylene (2), by a double cobalt-catalyzed cyclotrimerization strategy. [1] These hydrocarbons are the highest members of the, so far, five angular phenylene systems and, with 2, match the c