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Highly diastereoselective synthesis of 2-monosubstituted 1R,5S(1S,5R)-glycoluriles on the basis of S- and R-N-carbamoyl-α-amino acids

✍ Scribed by Angelina N. Kravchenko; Konstantin Yu. Chegaev; Il’ya E. Chikunov; Pavel A. Belyakov; Elena Yu. Maksareva; Konstantin A. Lyssenko; Oleg V. Lebedev; Nina N. Makhova


Book ID
119768113
Publisher
Royal Society of Chemistry
Year
2003
Tongue
English
Weight
580 KB
Volume
13
Category
Article
ISSN
0959-9436

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Diastereoselective synthesis of (1S,2S,3
✍ Elena Buñuel; Carlos Cativiela; Maria D. Diaz-de-Villegas 📂 Article 📅 1996 🏛 Elsevier Science 🌐 English ⚖ 430 KB

The tide compounds were prepared from key intermediates readily obtained by the stereoselective Diels-Alder reaction of (Z)-2-pbenyl-4-[(S)-2,2-dimethyl-l,3dioxolan-4-ylmethylene]-5(4H)-oxazolone, a chiral az-lactone derived from (R)glyceraldehyde and cyclopentadiene.