Highly diastereoselective reactions of (E)-cinnamyl chloride with aldehydes mediated by tin and aluminium
โ Scribed by James M. Coxon; Stephen J. van Eyk; Peter J. Steel
- Book ID
- 104226962
- Publisher
- Elsevier Science
- Year
- 1985
- Tongue
- French
- Weight
- 178 KB
- Volume
- 26
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
Highly diastereoselective reaction of cinnamyl chloride with aldehydes was achieved by the use of active zero-vale& tin generated in SnC12-Al system. Reactions of the well-designed allylic organometallics of silicon, chromium, boron, and etc with aldehydes provide the corresponding homoallylic alcoh
Allylindium reagents, prepared from excess allylic halide (Br or I) and indium metal, react with ฮฑ,ฮฒ-unsaturated ketones and aldehydes to give, after aerobic acidic workup, homoallyl-substituted vinylcyclopropanes. This process was explored and developed after a chance discovery arising from a side