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Highly Diastereoselective Intramolecular Allylation Reactions of Mixed Silyl-Substituted Acetals

โœ Scribed by Linderman, Russell J.; Chen, Kangyi

Book ID
127392369
Publisher
American Chemical Society
Year
1996
Tongue
English
Weight
460 KB
Volume
61
Category
Article
ISSN
0022-3263

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๐Ÿ“œ SIMILAR VOLUMES

A highly regioselective reaction of ally
A highly regioselective reaction of allylic acetates with silylated carbon nucleophiles directed by a sulfenyl group
โœ Kazuaki Kudo; Kazuhiko Saigo; Yukihiko Hashimoto; Hitoshi Houchigai; Masaki Hase ๐Ÿ“‚ Article ๐Ÿ“… 1991 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 158 KB

cx-Sulfenylmethyl)allyl acetates reacted with silylated carbon nucleophiles in the presence of a catalytic amount of a Lewis acid to give mainly a&ducts at the sulfenylmethyl group in moderate to good yields with high regioselectivity. The reaction may proceed via episulfonium ion intermediates.