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Highly Diastereoselective Catalytic Meerwein—Ponndorf—Verley Reductions.

✍ Scribed by Jingjun Yin; Mark A. Huffman; Karen M. Conrad; Joseph D. III Armstrong

Book ID
101983049
Publisher
John Wiley and Sons
Year
2006
Weight
35 KB
Volume
37
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

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## Abstract The new variation of the Meerwein‐Ponndorf‐Verley reduction using 1‐[4‐(dimethylamino)phenyl]ethanol (DMAPE) (6) or 1‐tetralol (12) (3 equiv.) as the reducing alcohols and Zr(O‐__t__Bu)~4~ as the catalyst (0.2 equiv.) is kinetically controlled and highly stereoselective. Preferential ax