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Highly Diastereo- and Enantioselective Reactions of Enecarbamates with an Aldehyde.

✍ Scribed by Ryosuke Matsubara; Paulo Vital; Yoshitaka Nakamura; Hiroshi Kiyohara; Shu Kobayashi


Publisher
John Wiley and Sons
Year
2005
Weight
53 KB
Volume
36
Category
Article
ISSN
0931-7597

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Highly Diastereo- and Enantioselective V
✍ Qian-Yi Zhao; Zhi-Liang Yuan; Min Shi 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 230 KB 👁 1 views

## Abstract A highly regio‐ and enantioselective asymmetric vinylogous Mannich reaction of readily available fluorinated aldimines bearing a chiral auxiliary [(__S__)‐1‐phenylethyl group] with siloxyfurans to afford chiral fluorine‐containing γ‐butenolide or γ‐lactone derivatives has been developed