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Highly Convergent Synthesis of a Rebeccamycin Analogue with Benzothioeno(2,3-a)pyrrolo(3,4-c)carbazole as the Aglycone.

✍ Scribed by Jianji Wang; Nachimuthu Soundarajan; Nian Liu; Kurt Zimmermann; B. Narasimhulu Naidu


Publisher
John Wiley and Sons
Year
2005
Weight
12 KB
Volume
36
Category
Article
ISSN
0931-7597

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Synthesis of indeno[2,1-a]pyrrolo[3,4-c]
✍ Robert L. Hudkins; Chung Ho Park πŸ“‚ Article πŸ“… 2003 πŸ› Journal of Heterocyclic Chemistry 🌐 English βš– 114 KB πŸ‘ 1 views

## Abstract Reported here is the synthesis and characterization of the indenopyrrolocarbazole ring system utilizing a Diels‐Alder reaction with 2‐indenylindole and maleimide. Clemmensen reduction of imide **10** furnished the 5‐oxo (**16**) and 7‐oxo (**17**) lactam regioisomers. A new regiospecifi